按要求完成下列方程式.(1)Fe(OH)3与KClO在强碱性条件下制取K2FeO4的离子方程式______.(2)与MnO2?

2025-03-29 04:58:06
推荐回答(1个)
回答1:

(1)次氯酸根离子具有强氧化性,能够将氢氧化铁氧化成FeO42-,FeO42-中铁元素的化合价为+6价,氢氧化铁中铁的化合价为+3价,铁化合价升高了3价,次氯酸根离子中Cl盐酸的化合价为+1价,被还原变成-1价的氯离子,化合价降低了2价,化合价变化的最小公倍数为6,则氢氧化铁的计量数为2、次氯酸根离子的计量数为3,然后根据观察法配平,该反应的离子方程式为:2Fe(OH)3+3ClO-+4OH-=2FeO42-+5H2O+3Cl-
故答案为:2Fe(OH)3+3ClO-+4OH-=2FeO42-+5H2O+3Cl-
(2)K2FeO4?Zn也可以组成碱性电池,K2FeO4在电池中作为正极材料,负极为锌失电子发生氧化反应,电极反应Zn-2e-+2OH-=Zn(OH)2;依据产物和电子守恒写出正极反应:FeO42-+3e-+4H2O=Fe(OH)3↓+5OH-
故答案为:FeO42-+3e-+4H2O=Fe(OH)3↓+5OH-
(3)CHCl3中碳为+2价,COCl2中碳为+4价,故H2O2中氧元素化合价由-1价降低为-2价,生成H2O,由电子转移守恒与原子守恒可知可知,CHCl3、H2O2、COCl2、H2O的化学计量数为1:1:1:1,根据原子守恒故含有HCl生成,故反应方程式为CHCl3+H2O2=HCl+H2O+COCl2
故答案为:CHCl3+H2O2=HCl+H2O+COCl2
(4)惰性电极电解氯化铝溶液时,阳极放电的为氯离子,氯离子失去电子生成氯气,阴极氢离子得到电子生成氢气,生成的氢氧根离子与氯离子反应生成氢氧化铝沉淀,反应达到离子方程式为:2Al3++6Cl-+6H2O=3H2↑+2Al(OH)3↓+3Cl2↑,
故答案为:2Al3++6Cl-+6H2O=3H2↑+2Al(OH)3↓+3Cl2↑;
(5)向NH4Fe(SO42溶液中滴加Ba(OH)2溶液至铁离子恰好沉淀,此时铵根离子没有参与反应,NH4Fe(SO42与Ba(OH)2的物质的量之比为2:3,反应生成硫酸钡沉淀和氢氧化铁沉淀,反应的离子方程式为:2Fe3++3SO42-+3Ba2++6OH-=3BaSO4↓+2Fe(OH)3↓,
故答案为:2Fe3++3SO42-+3Ba2++6OH-=3BaSO4↓+2Fe(OH)3↓.

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