(1)①已知:①N2(g)+2O2(g)=2NO2(g)△H=67.7kJ?mol-1 ②N2H4(g)+O2(g)=N2(g)+2H2O(g)△H=-543kJ?mol-1,由盖斯定律②×2-①得到,2N2H4(g)+2NO2(g)=3N2(g)+4H2O (g)△H=-1153.7kJ?mol-1,故答案为:2N2H4(g)+2NO2(g)=3N2(g)+4H2O(g)△H=-1153.7 kJ?mol-1; ②已知:①N2H4(g)+O2(g)=N2(g)+2H2O(g)△H=-543kJ?mol-1 ②1 2 H2(g)+1 2 F2(g)=HF(g)△H=-269kJ?mol-1 ③H2(g)+1 2 O2(g)=H2O(g)△H=-242kJ?mol-1 由盖斯定律①-③×2+②×4得到:2N2H4(g)+2F2(g)=N2(g)+4HF (g)△H=-1135kJ?mol-1;故答案为:N2H4(g)+2F2(g)=N2(g)+4HF(g)△H=-1135 kJ?mol-1;(2)①电池总反应与戊烷燃烧的方程式相同,都为氧化还原反应,方程式为C5H12+8O2→5CO2+6H2O,故答案为:C5H12+8O2→5CO2+6H2O; ②放电时,阴离子向负极移动,阳离子向正极移动,故答案为:负; ③电解硫酸铜,阳极生成氧气,阴极生成氢气,发生2CuSO4 +2H2O 电解 . 2H2SO4 +2Cu+O2↑,n(O2)=0.56L 22.4L/mol =0.025mol,n(Cu)=0.05mol, m(Cu)=0.05mol×64g/mol=3.2g, n(H2SO4)=0.05mol, c(H+)=0.1mol, pH=1,转移的电子的物质的量为0.025mol×4=0.1mol,故答案为:3.2;1;0.1.