推荐回答(1个)
非氧化性酸 由于绝大多数酸溶于水都能电离出H+,氢离子具有弱氧化性,所以,酸都有弱氧化性。
我们平常所说的非氧化性酸---是指在反应中只能表现出氢离子的弱氧化性的酸。如:HCl,HBr,H2CO3,稀H2SO4,磷酸等。
与氧化性酸---一般是含氧酸,是指酸中除了氢、氧元素之外的中心元素在化学反应中表现出强氧化性。比较常见的有:浓、稀硝酸,浓硫酸,次氯酸,氯酸,亚氯酸,高氯酸,亚硝酸等。
比氢离子氧化性强的含氧酸,其酸根里的中心原子处于较高的价态。反应中比氢离子易得电子。常见的氧化性酸有浓硫酸、浓硝酸、稀硝酸、亚硝酸及氯、溴、碘的含氧酸。从标准电极电势的数值上看,它们比氢
氧化性酸的强氧化性表现在:
①能与排在常见金属活动性顺序表中氢后面的金属单质反应,能将变价金属从零价氧化成较高的价态。例如:
Cu+2H2SO(浓)CuSO4+SO2↑+2H2O
3Ag+4HNO3(稀)3AgNO3+NO↑+2H2O
2Fe+6H2SO4(浓)Fe2(SO4)3+3SO2↑+6H2O
Fe+4HNO3(稀)Fe(NO3)3+NO↑+2H2O
②能与不太活泼的非金属单质反应,例如:
C+2H2SO4(浓)CO2↑+2SO2↑+2H2O
C+4HNO3(浓)CO2↑+4NO2↑+2H2O
P+5HNO3(浓)H3PO4↑+5NO2↑+H2O
I2+10HNO3(浓)2HIO3↑+10NO2↑+4H2O
③能与许多含较低价态元素的化合物反应,例如:
4HNO3(稀)+FeS=Fe(NO3)3+S↓+NO↑+2H2O
HClO+H2SO3=HCl+H2SO4
氧化性酸的氧化性强弱,存在以下规律:
①对于同一种氧化性酸,浓度越大(或溶液中氢离子浓度越大)氧化性越强。例如,浓硝酸比稀硝酸氧化性强。从电极电势上看,增大酸根或氢离子的浓度,氧化能力增强,例如:
硝酸根及氢离子浓度增大(尤其是氢离子浓度)电极电势的值变大。
②对于同一种元素形成的不同价态的含氧酸,一般低价态的比高价态的氧化性强,例如:
HClO>HClO2>HClO4
HNO2>HNO3
③同周期主族元素形成的最高价含氧酸,从左到右,氧化性依次增强,例如,高氯酸常温下氧化性很强,硫酸浓度大加热时才表现出强氧化性,磷酸则几乎无氧化性。相应的低价态含氧酸也有类似的规律,例如,氯酸比亚硫酸氧化性强,溴酸比亚硒酸氧化性强。
④同主族元素形成的同价态含氧酸,氧化性强弱的规律复杂,常见各族元素含氧酸的氧化性强弱顺序:
HBrO4≈H5IO6>HClO4
HBrO3>HClO3>HIO3
HClO>HBrO>HIO
H2SeO4≈H6TeO6>H2SO4
HNO3>H3AsO4>H3PO4
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